H Maria,
As far as I did, yes you can.
All you need to do when you come to Slovakia for your residence, go to the foreign police to register and get your 5 years residential visa but "let your husband ask first for the required papers for residential visa wether in Slovak embassy in Netherlands or in the foreign police office in Slovakia"
Then after investigating about both of you, if it's approved you will get your ID Slovak Card, take it and go to the labor office to register there "only to allow them to pay you the insurance until you find a job"
@Fookning also added that there is extra step with the PR office but frankly I didn't pass by this and I don't know about, but I'm waiting for her feedback for further info.
Good Luck Maria and have a nice day 
Adam Khaled